Rotary fluid processing systems and associated methods

ABSTRACT

Rotary fluid processing systems and associated methods are disclosed. A purification system in accordance with the particular embodiment includes a rotatable adsorbent-containing heat/mass transfer element that is generally symmetric about a rotation axis, and includes multiple radial flow paths oriented transverse to the rotation axis and multiple axial flow paths oriented transverse to the radial flow paths. The axial flow paths and radial flow paths are in thermal communication with each other, and are generally isolated from fluid communication with each other at the heat transfer element. Particular embodiments can further include a housing arrangement having multiple manifolds with individual manifolds having an entry port and an exit port, and with individual manifolds having different circumferential locations relative to the rotation axis. Still further embodiments can include a seal arrangement positioned between the heat transfer element and the housing arrangement to expose the radial flow paths, but not the axial flow paths, to the entry and exit ports of one of the manifolds, and expose the axial flow paths, but not the radial flow paths, to the entry and exit ports of another of the manifolds.

TECHNICAL FIELD

The present disclosure is directed generally to rotary fluid processing systems and associated methods, including rotary systems for removing impurities from methane-containing mixtures in a continuous flow process that employs limited valving.

BACKGROUND

Secure domestic energy supply, global warming and climate change are presently receiving significant scientific, business, regulatory, political, and media attention. According to increasing numbers of independent scientific reports, greenhouse gases impact the ozone layer and the complex atmospheric processes that re-radiate thermal energy into space, which in turn leads to global warming on Earth. Warmer temperatures in turn affect the entire ecosystem via numerous complex interactions that are not always well understood. Greenhouse gases include carbon dioxide, but also include other gases such as methane, which is about 23 times more potent than carbon dioxide as a greenhouse gas, and nitrous oxide, which is over 300 times more potent than carbon dioxide as a greenhouse gas.

In addition to the foregoing greenhouse gas concerns, there are significant concerns about secure domestic energy supplies, concerns that the United States imports over 60% of the crude oil it consumes from a few unstable regions of the globe, and concerns about the rate at which global oil reserves are being depleted. Accordingly, there is an increasing focus on finding alternative sources of energy, including renewable, less expensive, and domestic energy sources that are cleaner to produce and use. These sources include coal seam methane, coal mine gas, non-conventional gas from shale deposits, and stranded well gas. These energy sources also include the organic fractions of municipal solid waste, food processing wastes, animal wastes, restaurant wastes, agricultural wastes, and waste water treatment plant sludge.

Many of the foregoing organic waste streams can be converted to biogas via anaerobic bacteria to produce mixtures of methane. Examples include covered landfills where the landfill gas contains approximately 48% methane, 38% carbon dioxide, 12% nitrogen and oxygen, water vapor, and small amounts of numerous other compounds. Biogas from anaerobic digestion of organic waste streams consists of approximately 65% methane, 33% carbon dioxide, water vapor and small amounts of other compounds. Coal mine gas contains approximately 64% methane, 32% nitrogen, 3% carbon dioxide, water, and small amounts of other compounds. Non-conventional or shale gas contains approximately 90% methane, 8% ethane and propane, 2% carbon dioxide, water, and small amounts of other compounds. Stranded well gas has a wide range of compositions depending on the location but typically contains approximately 80% methane, 13% nitrogen, several percent ethane and propane, plus water and 2% carbon dioxide. These stranded or waste sources of methane are widely geographically distributed rather than in large, localized sources like a large gas field. With enhanced technology these distributed methane sources are being converted to liquid natural gas (LNG) for effective storage, transport, and distribution to industrial end users for more economical use of process heat fuel and transportation end users for economical and low emissions vehicle fuel for light and heavy duty vehicles.

The processes associated with producing both LNG and compressed natural gas from LNG (LCNG) include purifying the incoming methane gas stream to remove constituents such as those that freeze out in or otherwise degrade LNG process equipment. Among the well known purification techniques is selective adsorption of certain impurities on different adsorbents such as activated alumina or zeolites. In such adsorption techniques certain impurities in a process stream flowing within a vessel containing the adsorbent are physi-adsorbed onto the surface of the adsorbent thus removing the impurities from the process stream. This purification continues until the adsorbent is saturated. To continue purification of the process stream, the process stream must be switched to another identical vessel containing clean, cool adsorbent. This transfer between vessels is normally accomplished by opening and/or closing a combination of several valves to accomplish a semi-continuous purification of the process stream. In one type of adsorption purifier, the saturated adsorbent is heated by several hundred degrees Fahrenheit, e.g., to ˜500° F., to substantially decrease the selective adsorptivity of the adsorbent. This heating thereby releases the impurities from the adsorbent so they can be purged from the vessel into a discharge stream before the clean adsorbent is cooled and prepared for another purification step. The heating, purging, and cooling steps accomplish regeneration of the adsorbent. This common type of adsorption purification is called temperature swing adsorption. It commonly involves two or more vessels in parallel which are interconnected by a complex set of control valves on the inlets and outlets of each vessel. The four stages of a temperature swing adsorption purification cycle are sequentially executed in each vessel nominally over a minimum period of several hours, e.g., 12 hours. One good application of temperature swing adsorption purification is to remove the carbon dioxide present in the methane mixtures from most of the distributed waste or stranded sources. The carbon dioxide must be efficiently removed to a concentration of about 100 parts per million to avoid freezing out in the cryogenic heat exchanger, a core component of a plant that produces LNG. The small, distributed nature of methane mixtures from many stranded gas wells, biomass waste streams or landfills makes the capital and operating costs associated with such unmonetized gas-to-LNG plants a key contribution to the delivered price of industrial process LNG fuel or LNG or LCNG vehicle fuel. Accordingly, there is a need for better purifier technology that simplifies the purification steps, provides continuous purification with fewer components such as valves, and thereby reduces capital and operating costs of such LNG plants and results in a less expensive methane fuel.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a partially schematic plan view of a rotary gas processing system having axial and radial flow paths configured in accordance with an embodiment of the disclosure.

FIG. 2A is a partially schematic illustration of a system seal positioned to seal axial and radial flow paths in accordance with an embodiment of the disclosure, taken substantially along line 2A-2A of FIG. 1.

FIG. 2B is a partially schematic, cross-sectional illustration of a system seal positioned to seal axial flow paths in accordance with an embodiment of the disclosure, taken substantially along line 2B-2B of FIG. 1.

FIG. 2C is a partially schematic, cross-sectional illustration of a system seal positioned to seal radial flow paths in accordance with an embodiment of the disclosure, taken substantially along line 2C-2C of FIG. 1.

FIG. 3 is a partially schematic plan view of a rotary gas processing system having four regions configured in accordance with another embodiment of the disclosure.

FIG. 4 is a partially schematic, isometric view of an embodiment of the system shown in FIG. 3.

FIG. 5 is a partially schematic, isometric view of an embodiment of the system shown in FIG. 4, with an upper housing portion removed.

FIG. 6 is a partially schematic, isometric view of the system shown in FIG. 5 with selected seal portions removed.

FIG. 7 is a partially schematic, cut-away view of a system seal configured in accordance with an embodiment of the disclosure.

FIG. 8 is a partially schematic, cross-sectional view of an embodiment of the system shown in FIG. 4.

FIG. 9 is another partially schematic, cross-sectional view of an embodiment of the system shown in FIG. 4, illustrating a representative driver arrangement.

FIGS. 10A-10C illustrate a method for manufacturing a housing in accordance with an embodiment of the disclosure.

FIGS. 11A-11G illustrate representative internal arrangements of heat transfer elements in accordance with embodiments of the disclosure.

FIG. 12 is a graphical illustration of the temperature performance characteristics of an adsorbent heat transfer element configured in accordance with an embodiment of the disclosure.

DETAILED DESCRIPTION

Several aspects of the present disclosure are directed to rotary systems and associated methods for processing methane and other gases. Well-known characteristics often associated with certain features of these systems and methods have not been shown or described in detail to avoid unnecessarily obscuring the description of the various embodiments. Those of ordinary skill in the relevant art will understand that additional embodiments may be practiced without several of the details described below, and/or may include aspects in addition to those described below.

Several of the systems described below include a generally toroidal or donut-shaped heat/mass transfer element (e.g., a adsorbent processing medium) that rotates within a housing (e.g., a hermetic housing). As the heat/mass transfer element rotates, it sequentially exposes internal process fluid and heat transfer fluid flow passages within an associated processing medium (e.g., the adsorbent) to multiple manifolds. The multiple manifolds can (a) continuously supply a process fluid (e.g., methane gas mixture) to the processing medium which treats the process fluid (e.g., by removing impurities from the methane gas), and (b) continuously restore, replenish, regenerate or rejuvenate the processing medium before it processes additional fluid. This arrangement can be used to produce a continuous flow of processed fluid, with a reduced number of cyclic valves compared to similarly-functioning batch-mode purifying devices, or even zero valves (e.g., a valveless system), and other associated benefits that will be described in further detail below.

FIG. 1 is a partially schematic, top plan view of a system 100 configured in accordance with an embodiment of the disclosure. The arrangement shown in FIG. 1 includes several simplifications to facilitate a clear disclosure of the technology. In at least some embodiments, suitable systems can be manufactured with these simplifications incorporated. In other embodiments, additional features (discussed later) are typically employed, e.g., to provide an overall system efficiency level suitable for commercial use. The system 100 can include a generally ring-shaped or toroidal heat/mass transfer element 130 positioned within a correspondingly shaped hermetic housing 110. The housing 110 can remain fixed, while the heat/mass transfer element 130 rotates within the housing about a rotation axis 101 that extends out of the plane of FIG. 1. Accordingly, the heat/mass transfer element 130 can be axisymmetric relative to the rotation axis 101. A driver 190 is operatively coupled to the heat/mass transfer element 130 to provide the continuous rotary motion. The housing 110 can include multiple manifolds 111 (four are shown in FIG. 1 as a first manifold 111 a, a second manifold 111 b opposite the first manifold 111 a, a third manifold 111 c between the first and second manifolds 111 a, 111 b, and a fourth manifold 111 d opposite the third manifold 111 c) positioned at corresponding regions 112 (four are shown as a first region 112 a, a second region 112 b opposite the first region, a third region 112 c between the first and second regions 112 a, 112 b, and a fourth region 112 d opposite the third region 112 c). As the heat/mass transfer element 130 rotates about the rotation axis 101, as indicated by rotation direction arrow 104, each portion of the heat/mass transfer element 130 is sequentially exposed to each of the manifolds 111. The manifolds 111 collect and/or distribute fluid.

The heat/mass transfer element 130 includes both axial flow passages 131 and radial flow passages 132 that provide excellent thermal communication between the fluids they convey and an adsorbent processing medium 141, e.g., a adsorbent processing medium. However, the axial flow passages 131 are isolated from fluid communication with the radial flow passage 132. In the simplified schematic shown in FIG. 1, the intimate thermal communication between the fluids and the adsorbent processing medium 141 is somewhat obscured. Further details of representative embodiments that provide such thermal communication are described later with reference to FIGS. 11A-11G. At different manifolds, a flow of heat transfer fluid is permitted to pass through only the axial flow passages 131, or the process gas mixture is permitted to pass through only the radial flow passages 132, thus allowing effective contact between the adsorbent and different fluids in the two types of flow passages without mixing the flows in the two types of passages. Accordingly, a process fluid (e.g., an impure gas mixture) can be in intimate contact with the adsorbent processing medium 141 as it flows through the radial flow passages 132, and the adsorbent processing medium 141 can be regenerated by a hot or cold heat transfer fluid that flows through the axial flow passages 131. A seal arrangement 150 and relatively small pressure differences within the housing 110 prevent the different fluid streams from mixing within the housing around the heat/mass transfer element 130. Accordingly, the seal arrangement 150 can include full seals 151 between neighboring regions 112, and partial (e.g., axial flow only or radial flow only) seals within each region 112. Further details are described below at a general level with respect to FIGS. 2A-2C, and at a more detailed level with respect to FIGS. 3-12.

Continuing to refer to FIG. 1, the system 100 can be configured to perform a wide variety of processes on a wide variety of process gases or other fluids. Particular aspects of the system are described further below in the context of removing carbon dioxide and/or other impurities from a stream of methane gas. It will be understood by those of ordinary skill in the relevant art that similar systems and methods can be employed to perform other processes on other types of fluids. In general terms, particular embodiments of the disclosure are directed to performing an adsorption purification process on the process fluid at one or more regions (e.g., the first region 112 a), and then regenerating/restoring the processing medium 141 at other regions (e.g., the second, third and fourth regions 112 b, 112 c, 112 d).

In an embodiment shown in FIG. 1, an input process fluid 102 (e.g., a fluid having impurities) enters the first manifold 111 a at a first entry port 113 a. The input process fluid 102 passes radially outwardly through the heat/mass transfer element 130, as indicated by arrows R1. In the heat/mass transfer element 130, the input process fluid 102 can contact the processing medium 141 (e.g., an adsorbent) that removes certain impurities and thus purifies or otherwise treats the process fluid. For example, in a particular embodiment, the adsorbent can be configured to remove carbon dioxide, water, and/or hydrogen sulfide from a methane gas stream. The purified or otherwise processed fluid then exits the first manifold 111 a through an exit port 114 a, resulting in a flow of output process fluid 103.

As the heat/mass transfer element 130 rotates through the first manifold 111 a, the processing medium 141 can become gradually saturated with impurities or depleted or otherwise experience a reduction in its ability to remove impurities. For example, an adsorbent processing medium 141 can become saturated with the impurities removed from the input process fluid 102. Accordingly, the processing medium 141 can be regenerated to remove the adsorbed impurities at the third region 112 c. In a particular embodiment, the adsorbent processing medium 141 is regenerated by heating it to temperatures high enough to reduce the adsorptivity of impurities on the adsorbent to a negligible value thereby releasing the adsorbed impurities. Accordingly, the system 100 includes a heat transfer fluid flow path and heat exchanger arrangement 170 configured to heat the adsorbent processing medium 141 with a heat transfer fluid at the third region 112 c. In a particular embodiment, the heat exchanger arrangement 170 can include a heater 171 that directs a heated heat transfer fluid (e.g., a regeneration gas) into the third manifold 111 c through an entry port 113 c, and then through the axial flow passages 131 of the heat/mass transfer element 130 in an axial direction (e.g., perpendicular to the plane of FIG. 1) as indicated by arrows A1. The hot heat transfer fluid exits the third manifold 111 c at a corresponding exit port 114 c at a lower temperature, as a result of transferring heat to the heat/mass transfer element 130. The heat received by the heat/mass transfer element 130 at the third region 112 c releases the adsorbed impurities from the adsorbent processing medium 141.

As the heat/mass transfer element 130 continues to rotate, the adsorbent processing medium 141 is exposed to a hot purge gas at the second region 112 b. In particular, hot purge gas from a hot purge fluid supply 175 passes into the second manifold 111 b via an entry port 113 b, and travels radially inwardly through the radial flow passages 132, as indicated by arrows R2. The purge fluid removes the impurities released from the adsorbent processing medium 141 in the third region 112 c.

As the heat/mass transfer element 130 rotates further, the adsorbent processing medium 141 is exposed to the fourth manifold 111 d at the fourth region 112 d. In the fourth manifold 111 d, the hot, clean heat/mass transfer element 130 is cooled, to prepare the adsorbent processing medium 141 to adsorb additional impurities by the time it rotates into the first manifold 111 a. Accordingly, the heat exchanger arrangement 170 can include a cooler 172 that directs a cooled or cold heat transfer fluid into the fourth manifold 111 d via an entry port 113 d and through the axial flow passages 131 of the heat/mass transfer element 130, as indicated by arrows A2, to cool the heat/mass transfer element 130. The heat transfer fluid exits the third manifold 111 c via a corresponding exit port 114 d. As the heat/mass transfer element 130 continues to rotate, the cooled portion of the adsorbent processing medium 141 is again exposed to input process fluid 102 at the first region 112 a. Accordingly, each portion of the adsorbent processing medium 141 is sequentially exposed to the process fluid, put into good thermal contact with a hot regeneration fluid, exposed to a hot purging fluid, and put into good thermal contact with a cold regeneration fluid.

In most cases, it is expected that the heat exchanger 170 will operate in a closed loop fashion (as discussed later with reference to FIG. 3) for increased thermal regeneration efficiency. In a simplified aspect of an embodiment shown in FIG. 1, the heat exchanger arrangement 170 operates in an open loop fashion. Accordingly, the heater 171 heats a regeneration fluid that passes through the second manifold 111 b and is then disposed of. The cooling fluid separately passes through the fourth manifold 111 d and is then also disposed of.

In a simplified closed-loop embodiment, illustrated in dashed lines in FIG. 1 the same fluid (e.g., a gas) used to heat and regenerate the adsorbent processing medium 141 is then cooled and used to cool and regenerate the adsorbent processing medium 141. In this embodiment, the fluid used in the closed loop heat exchanger can be compatible with or the same fluid as the primary component of the process fluid so that in the event some of the heat exchanger fluid remains in the heat/mass transfer element 130 after hot and cold regeneration, it does not interfere with the purification process conducted at the first region 112 a or the purging process in the second region 112 b. For example, the heat transfer fluid can include pure methane gas when the input process fluid 102 includes methane gas containing impurities. A more complex closed-loop arrangement is described later with reference to FIG. 3.

FIGS. 2A-2C are cross-sectional illustrations of the heat/mass transfer element 130, the housing 110, and associated seals 150 employed at various points around the circumference of the housing 110 shown in FIG. 1. For example, FIG. 2A is a representative cross-sectional illustration of the housing 110 and the heat/mass transfer element 130 at one of the full seals 151 shown in FIG. 1. As shown in FIG. 2A, the heat/mass transfer element 130 includes radial process fluid flow paths or passages 132 that extend transverse to the rotation axis 101, and axial heat transfer fluid flow paths or passages 131 that extend generally parallel to the rotation axis 101. The radial flow passages 132 are positioned to allow contact (e.g., direct contact) between the adsorbent material and the process fluid, and the axial flow passages 131 are positioned in excellent thermal communication with the adsorbent material 141 described above, but are isolated from direct fluid communication with the process fluid in the heat/mass transfer element 130.

In a particular embodiment, both the hermetic housing 110 and the heat/mass transfer element 130 have generally toroidal shapes, but the inner surface of the housing 110 is circular while the outer surface of the heat/mass transfer element 130 is rectangular or, in particular embodiments, square. Accordingly, the seal arrangement 150 includes seals that are shaped to fit within the gap between these surfaces, while allowing the heat/mass transfer element 130 to rotate relative to the housing 110, and while preventing or at least significantly restricting circumferential flow between the axial flow passages 131 on the one hand and the radial flow passages 132 on the other. At the full seal 151, which is located between adjacent regions 112 (FIG. 1) of the system 100, no flow passes in either the axial direction or the radial direction. Accordingly, both the axial flow passages 131 and the radial flow passages 132 are shown in phantom lines in FIG. 2A. The full seal 151 can include an inner radial seal 153 a that seals against a first ring-shaped side 133 a of the heat/mass transfer element 130, and an outer radial seal 153 b that seals against a corresponding second ring-shaped side 133 b of the heat/mass transfer element 130. The full seal 151 can further include an upper axial seal 152 a that seals against a third ring-shaped side 133 c of the heat/mass transfer element 130, and a lower axial seal 152 b that seals against a fourth ring-shaped side 133 d of the heat/mass transfer element 130.

FIG. 2B illustrates a portion of the seal arrangement 150 at the first region 112 a and the second region 112 b. In the first region, the cool process fluid flows through the radial flow passages 132 (shown in solid lines) from the entry port 113 a to the exit port 114 a. Accordingly, the first and second sides 133 a, 133 b of the heat/mass transfer element 130 are exposed to the entry and exit ports 113 a, 114 a, while the upper axial seal 152 a and the lower axial seal 152 b seal the axial flow passages 131 (shown in phantom lines). As a result, the process fluid passes through the heat/mass transfer element 130 without entering the axial flow passages 131.

FIG. 2C illustrates the heat/mass transfer element 130 at the third region 112 c. In this region, the axial flow passages 131 are opened and the radial flow passages 132 are sealed. Accordingly, the inner radial seal 153 a and the outer radial seal 153 b seal the radial flow passages 132 from communication with the second manifold 111 b. The third and fourth sides 133 c, 133 d of the heat/mass transfer element 130 are exposed to the entry port 113 b and exit port 114 b to allow the regenerative heat transfer fluid to pass from the entry port 113 b to the exit port 114 b. A generally similar arrangement is used at the fourth region 112 d and fourth manifold 111 d (FIG. 1).

FIG. 3 is a more detailed, top plan schematic view of a system 300 configured in accordance with another embodiment of the disclosure. The system 300 has the same general arrangement described above with reference to FIG. 1 as well as several additional features. These additional features include (a) an arrangement of pressure equalization paths around the housing that allow different regions of the overall system 300 to operate at the same internal pressure despite large thermal transitions, and (b) additional closed loop heat exchanger arrangements that enhance the overall efficiency of the system. These aspects may be included all together on the same system as shown in FIG. 3, or these features may be selected individually or in other combinations in other embodiments.

The system 300 includes a heat/mass transfer element 330 and associated processing medium 341 that rotate within a housing 310 having four manifolds 311 a-311 d positioned at four corresponding circumferential regions 312 a-312 d. Each manifold 311 a-311 d has a corresponding entry port 313 a-313 d and exit port 314 a-314 d. At the first manifold 311 a, the input process fluid 102 is directed through the adsorbent processing medium 341 to produce an output process fluid 103 in a manner generally similar to that described above. At the third manifold 311 c, the adsorbent processing medium 341 is regenerated via heating, and at the fourth manifold 311 d, the adsorbent processing medium 341 is cooled, both in a manner generally similar to that described above. A heat exchanger arrangement 370 shown in FIG. 3 is configured in a closed loop so that the same heat transfer fluid used to heat the adsorbent processing medium 341 at the third region 312 c is used to cool the adsorbent processing medium 341 at the fourth region 312 d. A pump or blower 378 circulates the heat transfer fluid around the heat exchanger loop, through the cooler 172 (e.g., a trim cooler) and a trim heater 377 a. The heater 171 described above with reference to FIG. 1 has been combined with a regeneration fluid heat exchanger 377 that receives waste heat from a purge process fluid and a trim heater, described further below.

The second manifold 311 b is positioned opposite the first manifold 311 a, between the third manifold 311 c and the fourth manifold 311 d to purge desorbed contaminants from the heat/mass transfer element 330. Accordingly, the second manifold 311 b receives clean hot purge fluid (e.g., clean methane) from a heated purge fluid supply 375 and directs the hot purge fluid through the radial flow passages 332, as indicated by arrows R2. As the clean hot purge fluid passes through the radial flow passages 332 of the heat/mass transfer element 330, it carries out desorbed contaminants (e.g., carbon dioxide) from the adsorbent processing medium 341. Because the heat/mass transfer element 330 and adsorbent processing medium 341 have been heated (e.g., to about 500° F.) at the third region 312 c, the purge fluid is heated to the same hot temperature before passing through the adsorbent processing medium 341 in the second region 312 b. The hot purge fluid can accordingly be used to preheat the heat transfer fluid at the regeneration fluid heat exchanger 377 and trim heater 377 a before the heat transfer fluid enters the third region 312 c. The used and still hot purge fluid can also pass through a purge fluid heat exchanger 374 where it preheats the clean incoming purge fluid before the incoming purge fluid enters the second manifold 311 b. After passing through the purge fluid heat exchanger 374, the cooled used purge fluid can be used as fuel for a power generator for the system or otherwise beneficially disposed of. In a particular embodiment, the purge fluid is received from a purge fluid supply 373 that is drawn off the output process fluid 103. Accordingly, the purge fluid can include purified methane. After passing through the purge fluid heat exchanger 374, the purge fluid can pass through a trim heater 374 a to reach a suitably high temperature before entering the second region 312 b. Even after mixing with the desorbed contaminants at the second region 312 b, the used purge fluid can still be burned to produce power, for example, at a genset 307 or other device.

One feature of the arrangement shown in FIG. 3 is that the heat/mass transfer element 330 and the associated adsorbent processing medium 341 undergo significant thermal changes as the heat/mass transfer element 330 rotates through a complete cycle. For example, the temperature of the adsorbent processing medium 341 at the third region 312 c can reach about approximately 500° F. during a representative desorption process. As a result, the desorbed impurities will incrementally begin to increase the pressure in the hot processing medium segments containing the adsorbent. However, the radial flow passages 332 are generally sealed in the third region 312 c (e.g., as shown in FIG. 2C) so that the pressure in the processing medium segment could increase by the ratio of the average absolute temperatures in region 312 a and 312 c. Accordingly, to avoid such a pressure increase the system 300 can include features to reduce or prevent pressure differences that could cause leakage of fluids between different regions through the seals. These features can include multiple pressure equalization paths 315, e.g., a first pressure equalization path 315 a that couples the adsorbent and radial flow passages 332 at the third region 312 c with the exit port 314 b at the second region 312 b. Accordingly, desorbed fluids and residual process fluid within the radial flow passages 332 at the third region 312 c can mix with the desorbed fluids purged at the second region 312 b, and exit the system 100, while at the same time reducing or eliminating pressure differences that may build up in the third region 312 c as a result of heating for regeneration. In a particular embodiment, the first pressure equalization path 315 a can include a one-way valve 316 that prevents purged contaminants from reentering the heat transfer element 330. The first pressure equalization path 315 a can accordingly equalize the pressure between the third region 312 c and the second region 312 b without contaminating the heat/mass transfer element 330.

The system 300 can include other pressure equalization paths that operate in a generally similar manner to equalize pressures at other points around the circumference of the housing 310. For example, the heat/mass transfer element 330 will cool and the pressure of the residual gas in the adsorbent and radial flow segments 332 will decrease at the fourth region 312 d. To reduce or prevent pressure differences between the wheel segments of the heat/mass transfer element 330, the system 300 can include a second pressure equalization path 315 b and one-way valve 316 connected between the exit port 314 a of the first manifold 311 a, and the radial flow passages 332 within the fourth manifold 311 d. This arrangement will allow an adequate amount of purified process fluid to enter the adsorbent in the radial flow passages 332 at the fourth manifold 311 d, thus continuously equalizing the pressure between these two regions during cooling in the regeneration.

An advantage of the foregoing arrangement is that the entire system 300 can be operated at a single generally uniform internal pressure. For example, the internal pressure of the hermetic housing 310 can have a value of from about 80 psia to about 150 psia, and in a particular embodiment about 120 psia. In other embodiments, the internal pressure can be higher than 150 psia (e.g., 300-350 psia) provided the housing 310 and associated fluid paths and systems are designed to withstand such loads. By equalizing the internal pressure among the regions 312 a-312 d, the structural stresses on the system components and in particular, the demands placed on the seals, can be reduced or eliminated. Accordingly, it is expected that this arrangement will be more cost effective over the life of the system 300.

Another advantage of the foregoing arrangement is that the system 300 can operate in a continuous flow manner. In particular, input process fluid can be continuously supplied to the system 300 as the heat/mass transfer element 330 rotates, and the heat exchanger arrangement 370 can continuously operate to thermally regenerate the adsorbent processing medium 341. To facilitate a continuous operation, the sizes of the processing regions 312 a-312 d can be determined in a manner that enhances (e.g., optimizes) the overall efficiency of the system 300. For example, the adsorbent processing medium 341 may require less time to undergo the purge operation in the second region 312 b than it requires to perform the contaminant removal adsorption process in the first region 312 a. Accordingly, because the heat/mass transfer element 330 is expected to rotate continuously at a constant rate, the circumferential extent of the second region 312 b can be less than the circumferential extent of the first region 312 a, and is typically the smallest of the four regions. The adsorbent processing medium 341 may require more time at the third region 312 c for heating and desorption, than at the fourth region 312 d for cooling. Depending on factors that include specific flow rates and heat transfer coefficients, the circumferential extents of the third region 312 c and the fourth region 312 d can be greater or lesser than that of the first region 312 a.

FIGS. 4-11F illustrate particular features associated with particular embodiments of the system 300 to carry out the processes described above. Beginning with FIG. 4, the system 300 includes a donut-shaped hermetic housing 310 that includes an upper housing portion 317 a and a lower housing portion 317 b. Each of the housing portions 317 a, 317 b includes a flange 319 that extends outwardly and is used to removably connect (e.g., bolt) the two housing portions together with a hermetic sealant circumferentially inside the flange bolt circle. The housing 310 encloses the four processing regions 312 a-312 d, which are generally bounded (e.g., welded) as indicated by dashed lines in FIG. 4. A selected number of entry and exit ports are visible in FIG. 4, including the first exit port 314 a at the first region 312 a, the second entry port 313 b at the second region 312 b, the third entry port 313 c at the third region 312 c, and the fourth exit port 314 d at the fourth region 312 d. Hermetic bearing ports 318 allow access to circumferentially positioned bearings, which are described in greater detail later with reference to FIG. 8. The bearings allow the heat/mass transfer element 330 (not visible in FIG. 4) to rotate smoothly within the housing 310. Power is provided to the heat/mass transfer element 330 via a driver 190 contained in a driver housing 191.

FIG. 5 illustrates an embodiment of the system 300 shown in FIG. 4, with the upper housing portion 317 a removed. Accordingly, the heat/mass transfer element 330 and the seal arrangement 350 are visible in FIG. 5. The seal arrangement 350 includes four full seals 351 that prevent flow in both the radial and axial directions through the heat/mass transfer element 330. The seal arrangement 350 also includes the axial and radial seals described above. Several of the seals are visible in FIG. 5, including the upper axial seals 352 a at the first and second regions 312 a, 312 b, and the inner and outer radial seals 353 a, 353 b at the third and fourth regions 312 c, 312 d.

FIG. 6 illustrates the seal arrangement 350 with portions removed to expose features below. In particular, the radial and axial seals can include a volume of high-temperature foam 354 that is positioned over multiple circumferentially extending tubes 356. The tubes 356 are positioned against a seal sheet 355. When the high temperature foam 354 is compressed between the first housing portion 317 a (FIG. 4) and the second housing portion 317 b, it presses against the tubes 356, which in turn locally press on the seal sheet 355 to form a labyrinth seal with the heat/mass transfer element 330 just below. In a particular embodiment, the tubes 356 can be hollow. In further particular embodiments, the tubes 356 can include a fluid that is selectively pressurized to vary the local force provided by the tubes 356 against the seal sheet 355. The seal sheet 355 can include Rulon® or another suitable durable low-friction material.

FIG. 7 is a detailed, partially cut-away illustration of one of the full seals 351 described above. The full seals 351 can extend entirely around the heat/mass transfer element 330 and can include a pair of seal supports 357 positioned on opposite sides of a series of seal elements 358. The seal elements 358 can form a labyrinth seal around all sides of the heat/mass transfer element 330. The heat/mass transfer element 330 can include generally pie-shaped segments 334 that contain the axial and radial flow passages and the adsorbent processing medium, as will be described in further detail later with reference to FIGS. 11A-11G.

FIG. 8 is a partially schematic, cut-away view of the system 300 taken generally along line 8-8 of FIG. 4. FIG. 8 illustrates the structure located inside the bearing ports 318, including bearings 320 that engage the outer peripheral surface of the heat/mass transfer element 330. The bearing port 318 allows a manufacturer or user to adjust the bearing 320 to appropriately guide the heat/mass transfer element 330 as it rotates within the housing 310.

FIG. 9 is a partially schematic, cut-away illustration of the system 300 illustrating further details of the driver 390. The driver 390 is positioned within the driver housing 391 and can include a motor 392 or other motive element coupled to a shaft 393 that extends upwardly into the housing 310. The shaft 393 can include a pinion 394 that meshes with a corresponding rack 395 carried by the heat/mass transfer element 330. In other embodiments, the driver 390 can be operatively coupled to the heat/mass transfer element 300 with other suitable arrangements, e.g., a belt or chain drive. The heat/mass transfer element 330 can be supported in the housing 310 via the bearings 320 described above with reference to FIG. 8, and via low-friction axial supports 321. The driver 390 can include an appropriate gear reduction arrangement to rotate the heat/mass transfer element at an appropriate rate. In a particular example, the heat/mass transfer element 330 rotates at about one revolution per hour. The rate selected for rotating the heat/mass transfer element 330 can depend upon a variety of design factors, including the overall size of the system 300 and the flow rates of fluids through the system.

As described above, the housing 310 can have a ring shape and in particular embodiments, a toroidal or donut shape. The housing 310 can be manufactured using a variety of techniques, a representative one of which is shown in FIGS. 10A-10C. In this embodiment, the housing is assembled using multiple pre-formed pipe sections, as shown in FIG. 10A. The pipe sections can include multiple elbow sections 322 that each extend circumferentially around a fraction of a circle. As shown in FIG. 10B, four such elbow sections 322, each extending circumferentially through a 90° arc can be connected to each other using welds 323, forming a closed, annular, ring-shaped conduit. The assembled sections 322 can then be cut at a parting plane 324 to form the upper housing portion 317 a and the lower housing portion 317 b, shown in FIG. 10C. The manufacturer can then add a flange 319 to each of the two housing portions 317 a, 317 b to allow the housing portions to be releasably attached to each other with appropriate sealing material between the flanges on the housing and around the heat/mass transfer element 330 (FIG. 9). It is expected that this manufacturing technique can be significantly less expensive than others, including techniques that require the entire housing 310 to be formed from a single piece of stock. It is also expected that the circular cross-sectional shape of the housing 310 can efficiently hermetically contain the internal pressure loading without significantly bowing or otherwise potentially compromising the integrity of the seal arrangement and/or the rotation of the heat/mass transfer element. However, in at least some embodiments, the housing 310 may have a different cross-sectional shape, e.g., a square or rectangular cross-sectional shape e.g., for applications with relatively low internal pressure differentials between the region inside the housing and the region outside the housing such that little or no distortion of the housing occurs and it remains close fitting to the heat/mass transfer element.

FIGS. 11A-11G illustrate representative techniques for positioning an adsorbent processing medium 341 in the segments 334 of the heat/mass transfer element 330 described above with reference to FIG. 7. In general, the adsorbent processing medium 341 is in direct fluid contact with a fluid (e.g., an impure process mixture) passing through one of (a) the axial passages or (b) the radial passages, and is in good thermal communication (but not direct fluid communication) with heat transfer fluid passing through the other of (a) the axial passages or (b) the radial passages.

Beginning with FIG. 11A, a representative segment 334 a can include axial tubes 335 having outer surfaces with an adsorbent processing medium coating 336. The adsorbent processing medium 341 can include any appropriate absorbent that selectively removes certain impurities from process gas streams in particular embodiments, e.g., zeolites or activated alumina or activated carbon material in further particular embodiments. The axial tubes 335 are packed close together so as to be in line-to-line or point-to-point contact with each other. A process fluid flow 305 passes through the adsorbent processing medium 341 in a radial direction R. The hot or cold regenerating fluid (e.g., heat transfer fluid) can then pass through the axial tubes 335 in an axial direction (e.g., perpendicular to the plane of FIG. 11A) to heat or cool the adsorbent processing medium 341. The impurities are removed by a purge gas flow in direct contact with the hot adsorbent in the radial direction R.

FIG. 11B illustrates a representative segment 334 b having another arrangement in which the axial tubes 335 are packed with small adsorbent processing medium beads 337. In this embodiment the process fluid flows axially through the tubes 335 to contact the adsorbent processing medium 341 inside, and the hot or cold regenerating fluid flows radially among the tubes as indicated by arrow R. The purge fluid also flows axially through the tubes 335 to remove the desorbed impurities.

In FIG. 11C, a generally standard arrangement of a cross-flow heat exchanger grid material is positioned within a representative segment 334 c. Either the axial or the radial flow passages are then packed with the adsorbent processing medium. An advantage of this arrangement is that it is relatively simple to obtain a suitable cross-flow heat exchanger grid material and cut it to a rectangular size that fits within the segment 334 c. However, this arrangement creates dead spaces 340 in which the heat exchanger grid cannot be positioned without blocking the radial flow passages near the circumferential boundaries of the segment 334. Accordingly, an advantage of the arrangements described above with reference to FIGS. 11A and 11B is that they do not include a dead space 340. Put another way, a standard rectangular cross-flow heat exchanger grid does not readily fit in the tapered annular space of the segments 334, while the axially extending tubes shown in FIGS. 11A and 11B do.

FIG. 11D illustrates a segment 334 d having axially extending tubes 335 that carry a hot or cold regeneration fluid, and extend through axially layered highly thermally conducting screens 338. The screens 338 include a fine mesh having mesh openings that can each support an individual adsorbent processing medium bead 337. Accordingly, the process fluid flow 305 is directed radially over and around the adsorbent beads 337, while the regeneration fluid flow is directed axially through the axial tubes 335 such that the screen efficiently indirectly heats or cools the adsorbent beads as they rotate through the regenerative sections of the temperature swing adsorption cycle. FIG. 11E is a cross-sectional view of one of the tubes 335 shown in FIG. 11D and further illustrates the location of the adsorbent processing medium beads 337 between layers of screen 338.

FIG. 11F illustrates a segment 334 f that includes multiple tapered tubes 339 extending radially outwardly. Each of the tapered tubes 339 can include an arrangement of adsorbent processing medium beads 337 that are also arranged in a radially outward direction. The adsorbent processing medium beads 337 can have different diameters to take advantage of the increasing width (in a radially outward direction) of the tapered tubes 339. Accordingly, smaller beads 337 can be positioned radially inwardly in each tube 339, and larger beads 337 can be positioned radially outwardly. Process fluid 305 flows radially outwardly (or inwardly), and regeneration fluid flows axially in spaces between neighboring tapered tubes 339.

FIG. 11G illustrates still a further embodiment of a segment 334 g having a volume of adsorbent processing medium beads 337 that are not segregated into axial flow paths and radial flow paths. Accordingly, the process fluid flow 305 can be directed in a radial direction in the first region 312 a (FIG. 3), and the regeneration fluid can be directed in an axial direction in the third region 312 c (FIG. 3). Because this arrangement does not segregate the process fluid from the regeneration fluid, there will be mixing of these fluids and the purification efficiency of the arrangement is expected to be lower than the arrangements described above with reference to FIGS. 11A-11F.

One feature of the arrangements described above with reference to FIGS. 11A-11F is that they include a large amount of surface area per unit volume and accordingly have a high heat transfer effectiveness. In particular embodiments, these arrangements are expected to have specific areas in the range of 4,000-5,000 m²/m³ and/or an NTU (number of heat transfer units) in the range of 200 to 500. As a result, the regenerative heat transfer fluid can efficiently transfer heat to the adsorbent processing medium 341 during a hot regeneration process, and from the adsorbent processing medium 341 during a cold regeneration process. An advantage of this arrangement is described below with reference to FIG. 12.

FIG. 12 shows a representative third region 312 c of the system 300 described above with reference to FIG. 3, along with temperature profiles taken at a variety of circumferential locations within the third region 312 c. In a particular embodiment, hot gas is supplied in an axially downward direction at about 500° F. Due to the large surface area in the heat/mass transfer element 330, the gas exits the heat/mass transfer element 330 at about 90° F. within the third region 312 c until just before the segment exits the third region 312 c. FIG. 12 illustrates the temperature profiles e.g., the temperature front or boundary above which temperatures are about 500° F. and below which temperatures are at about 90° F. As shown in FIG. 12, the temperature front is quite sharp and quite flat, characteristic of excellent heat transfer between the hot regeneration fluid and the heat/mass transfer element 330. Accordingly, the adsorbent processing medium of the heat/mass transfer element 330 is at a uniformly high temperature as it exits the third region 312 c, and the heat transfer gas exiting the third region 312 c does not undergo a significant temperature rise except near the end of the third region 312 c. For example, the average temperature of the total collective heat transfer gas exiting the manifold over the third region 312 c can be about 120° F. This sharp heat transfer wave propagating during the regeneration process significantly reduces the amount of cooling that must be provided to the heat transfer gas prior to introducing the cold regenerative heat transfer gas at the fourth region 312 d (FIG. 3) e.g., at a temperature of about 68° F. to cool the heat/mass transfer element 330. Similarly, the high surface area of the heat/mass transfer element 330 causes the regenerative heat transfer gas to come out of each segment of the wheel at about 500° F. except near the exit of the fourth region such that the average temperature out of the manifold over the fourth region 312 d of the housing is about 450° F., significantly reducing the heating requirements for the regeneration fluid heat exchanger 377 and trim heater 377 a (FIG. 3), which increases the temperature of the heat transfer gas to about 500° F. before it re-enters the third region 312 c. Accordingly, the majority of the hot and cold thermal energy required for regeneration of the adsorbent is recycled through the system 300 to significantly improve the overall thermal efficiency of the temperature swing adsorption purifier system.

From the foregoing, it will be appreciated that specific embodiments of the disclosure have been described herein for purposes of illustration, but that various modifications may be made without deviating from the disclosure. For example, several aspects of the disclosure were described in the context of processing methane to remove carbon dioxide. In other embodiments, similar systems and methods can be used to process other gases. In addition, the processes undergone by those gases need not be limited to absorption or impurity removal processes. For example, the adsorbent processing medium described above can be replaced with a processing medium having a catalyst that initiates a reaction in the process gas. One such reaction can include the combination of methane with oxygen to form carbon dioxide and water. In still further embodiments, additional heat transfer aspects can be added to the system, for example, to further cool the adsorbent processing medium (and increase its adsorptivity) before it passes into the first region described above. In particular embodiments, the radial and/or axial flow passages or paths are distributed uniformly around the heat transfer elements, and in other embodiments, the axial and/or radial flow passages/paths can be distributed non-uniformly.

In still further embodiments, the system need not include an adsorbent processing medium at all, and can instead perform processes entirely on the basis of heat transfer. For example, the heat/mass transfer element can be replaced with a heat transfer element that is cooled to cryogenic temperatures at the fourth region, and that can remove carbon dioxide from a methane gas stream by causing the carbon dioxide to precipitate and freeze on the walls of the radial (or axial) flow passages. At the third region, the carbon dioxide can be driven (e.g., sublimated) from the heat transfer element by heating the heat transfer element as discussed above. In particular embodiments, the radial and/or axial flow passages or paths are distributed uniformly around the heat transfer element, and in other embodiments, the axial and/or radial flow passages/paths can be distributed non-uniformly. More generally, the heat/mass transfer element can be replaced with an element that performs either heat transfer or mass transfer but not necessarily both.

Certain aspects of the disclosure described in the context of particular embodiments may be combined or eliminated in other embodiments. For example, certain embodiments need not include a closed loop heat exchanger arrangement, and/or need not include a purge zone. Several embodiments were described above in the context of process fluids and heat transfer fluids that include gases. In other embodiments, the process fluids and/or the heat transfer fluids can include liquids. Further, while advantages associated with certain embodiments have been described in the context of those embodiments, other embodiments may also exhibit such advantages. Not all embodiments needs necessarily exhibit such advantages to fall within the scope of the present disclosure. Accordingly, the disclosure and associated technology can encompass other embodiments not expressly described or shown herein. 

We claim:
 1. A gas processing system, comprising: a housing arrangement having multiple manifolds, with individual manifolds having an entry port and an exit port, and with individual manifolds having different circumferential locations relative to a rotation axis; a heat/mass transfer element containing an adsorbent, positioned within the housing arrangement and rotatable relative to the housing arrangement about the rotation axis, the heat/mass transfer element including: multiple radial flow paths oriented transverse to the rotation axis; and multiple axial flow paths oriented transverse to the radial flow paths, the axial flow paths being in thermal communication with the radial flow paths, the axial flow paths being generally isolated from fluid communication with the radial flow paths at the heat/mass transfer element; at least one heat transfer loop between successive manifolds, wherein the adsorbent is heated and cooled between the successive manifolds; and a seal arrangement positioned between the heat/mass transfer element and the housing arrangement to expose the radial flow paths but not the axial flow paths to the entry and exit ports of one of the manifolds, and expose the axial flow paths but not the radial flow paths to the entry and exit ports of another of the manifolds.
 2. The system of claim 1 wherein the housing arrangement includes a first manifold, a second manifold, a third manifold and a fourth manifold, and wherein the seal arrangement is positioned between the heat/mass transfer element and the housing arrangement to expose the radial flow paths but not the axial flow paths to the first and second manifolds as the heat/mass transfer element rotates, and expose the axial flow paths but not the radial flow paths to the third and fourth manifolds as the heat/mass transfer element rotates.
 3. The system of claim 2 wherein the third manifold is positioned between the first and second manifolds, and wherein the fourth manifold is positioned between the first and second manifolds opposite the second manifold, and wherein a point on the heat/mass transfer element is sequentially exposed to the first, third, second and fourth manifolds as the heat/mass transfer element rotates about the rotation axis.
 4. The system of claim 2, further comprising a first fluid channel connected between the second and third manifolds to equalize a pressure between the second and third manifolds, and a second fluid channel connected between the first and fourth manifolds to equalize a pressure between the first and fourth manifolds.
 5. The system of claim 1 wherein the heat/mass transfer element includes an adsorbent processing medium positioned along the axial flow paths or the radial flow paths, and wherein the processing medium includes zeolite.
 6. The system of claim 1 wherein the heat/mass transfer element includes an adsorbent material positioned along the axial flow paths or the radial flow paths.
 7. The system of claim 6 wherein the axial flow paths include axially extending tubes, and wherein the adsorbent material is positioned on outer surfaces of the tubes.
 8. The system of claim 1 wherein the housing arrangement includes a housing having a generally toroidal shape with a circular cross-section.
 9. The system of claim 1 wherein the housing arrangement includes a continuous circular element disposed around the rotation axis.
 10. The system of claim 1, further comprising a fluid channel connected between the individual manifolds to equalize a pressure between the individual manifolds.
 11. The system of claim 1 wherein the heat/mass transfer element has a generally toroidal shape with a rectangular or square cross-section.
 12. The system of claim 11 wherein the heat/mass transfer element includes a first ring-shaped side at a first radial distance from the rotation axis, a second ring shaped side generally parallel to the first side and located at a second radial distance from the rotation axis, a third ring-shaped side oriented transverse to the first and second sides at a first axial location, and a fourth ring-shaped side oriented transverse to the first and second sides at a second axial location spaced apart from the first axial location, and wherein the radial flow paths extend from the first surface to the second surface, and wherein the axial flow paths extend from the third surface to the fourth surface.
 13. The system of claim 1 wherein the radial flow paths are distributed in a generally uniform, continuous manner around the rotation axis.
 14. The system of claim 1 wherein the axial flow paths are distributed in a generally uniform, continuous manner around the rotation axis.
 15. The system of claim 1 wherein individual manifolds are in fluid communication with the heat/mass transfer element over unequal circumferential extents.
 16. The system of claim 1, further comprising a driver coupled to the heat/mass transfer element to rotate the heat/mass transfer element about the rotation axis.
 17. The system of claim 16 wherein the heat/mass transfer element includes a rack, and wherein the driver is coupled to a pinion that is rotatably meshed with the rack.
 18. The system of claim 1 wherein the heat transfer loop is positioned to direct the heat transfer fluid through the axial flow paths but not the radial flow paths.
 19. A gas purification system, comprising: a toroidal housing having a first manifold, a second manifold opposite the first manifold, a third manifold between the first and second manifolds, and a fourth manifold opposite the third manifold, each manifold having an entry port and an exit port; a toroidal heat/mass transfer ring positioned within the housing and rotatable relative to the housing about a rotation axis, the heat/mass transfer ring including: multiple radial flow paths oriented along radii extending outwardly from the rotation axis; multiple axial flow paths oriented generally parallel to the rotation axis, the axial flow paths being in thermal communication with the radial flow paths, the axial flow paths being generally isolated from fluid communication with the radial flow paths at the heat/mass transfer ring; and an adsorbent material positioned within or along the radial flow paths; a seal arrangement positioned between the heat/mass transfer ring and the housing to expose the radial flow paths but not the axial flow paths to the entry and exit ports of the first and second manifolds as the heat/mass transfer ring rotates, and expose the axial flow paths but not the radial flow paths to the entry and exit ports of the third and fourth manifolds as the heat/mass transfer ring rotates; a driver operatively coupled to the heat/mass transfer ring to rotate the heat/mass transfer ring relative to the housing about the rotation axis; a process gas supply coupled to the entry port of the first manifold to direct process gas through the adsorbent; a purge gas supply coupled to the entry port of the second manifold to direct purge gas through the adsorbent; and a heat transfer loop coupled between the third and fourth manifolds to heat the adsorbent at the third manifold as the adsorbent rotates from the first manifold to the second manifold, and cool the adsorbent at the fourth manifold as the adsorbent rotates from the second manifold to the first manifold.
 20. The system of claim 19, further comprising: a heater positioned in the heat transfer loop to heat fluid entering the third manifold; and; a cooler positioned in the heat transfer loop to cool fluid entering the fourth manifold.
 21. The system of claim 19 wherein the heat/mass transfer ring includes a rack, and wherein the driver includes a motor coupled to a pinion that is rotatably meshed with the rack.
 22. A heat and mass transfer system, comprising: a rotatable heat/mass transfer element that is generally symmetric about a rotation axis, the heat/mass transfer element including: multiple radial flow paths oriented transverse to the rotation axis, the radial flow paths comprising an adsorbent distributed along the radial flow paths; and multiple axial flow paths oriented transverse to the radial flow paths, the axial flow paths being in thermal communication with the radial flow paths, the axial flow paths being generally isolated from fluid communication with the radial flow paths at the heat/mass transfer element; a toroidal housing having, a first manifold, a second manifold opposite the first manifold, a third manifold between the first and second manifolds, and a fourth manifold opposite the third manifold, each manifold having an entry port and an exit port, wherein the heat/mass transfer element is positioned within the housing; a seal arrangement positioned between the heat/mass transfer element and the housing, arrangement to expose the radial flow paths but not the axial flow paths to the entry and exit ports of the first and second manifolds as the heat transfer ring rotates, and expose the axial flow paths but not the radial flow paths to the entry and exit ports of the third and fourth manifolds as the heat/mass transfer element rotates; a driver operatively coupled to the heat/mass transfer element to rotate the heat/mass transfer element relative to the housing about the rotation axis; a process gas supply coupled to the entry port of the first manifold to direct process gas through the adsorbent; a purge gas supply coupled to the entry port of the second manifold to direct purge gas through the adsorbent; and a heat transfer loop coupled between the third and fourth manifolds to heat the adsorbent at the third manifold as the adsorbent rotates from the first manifold to the second manifold, and cool the adsorbent at the fourth manifold as the adsorbent rotates from the second manifold to the first manifold.
 23. The system of claim 22, further comprising an adsorbent material positioned along the axial flow paths.
 24. The system of claim 23 wherein the radial flow paths include radially-extending tubes, and wherein the adsorbent material is positioned within the tubes.
 25. The system of claim 23 wherein the axial flow paths include axially extending flow tubes, and wherein the adsorbent is positioned on outer surfaces of the tubes.
 26. A heat and mass transfer system, comprising: a generally toroidal housing having an internal volume, the internal volume including a first manifold at a first circumferential location, a second manifold at a second circumferential location, a third manifold at a third circumferential location, and a fourth manifold at a fourth circumferential location, each manifold having an entry port and an exit port extending through the housing; a seal arrangement positioned within the housing, the seal arrangement including a radially inward seal and a radially outward seal at each of the first and third manifolds, the seal arrangement further including first and second axial seals positioned at different axial locations, at each of the second and fourth manifolds a heat transfer loop coupled between the third and fourth manifolds; a heater positioned in the heat transfer loop to heat fluid entering the third manifold; and a cooler positioned in the heat transfer loop to cool fluid entering the fourth manifold.
 27. The system of claim 26, further comprising an adsorbent-containing heat/mass transfer element positioned within and rotatable relative to the housing, the heat/mass transfer element including multiple radial flow paths oriented transverse to the rotation axis and multiple axial flow paths oriented transverse to the radial flow paths, the axial flow paths being in thermal communication with the radial flow paths, the axial flow paths being generally isolated from fluid communication with the radial flow paths at the heat/mass transfer element.
 28. The system of claim 26, further comprising a fluid channel connected between the individual manifolds to equalize a pressure between the individual manifolds.
 29. The system of claim 26, further comprising a first fluid channel connected between second and third manifolds to equalize a pressure between the second and third manifolds, and a second fluid channel connected between first and fourth manifolds to equalize a pressure between the first and fourth manifolds. 